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Preheat your oven to broil. Line a rimmed baking sheet with aluminum foil and spray with cooking spray.
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In a small bowl, mix together the chili powder, paprika, sugar, and salt
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Generously sprinkle the chili powder mixture evenly over the tops of the salmon fillets.
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Place the salmon on the prepared baking sheet and broil for 6-9 minutes, depending on how thick your fillets are and how crispy you prefer the crust.
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Remove the salmon from the oven and brush the maple syrup over the tops to coat the spice rub. Return to the oven and broil for an additional 1-2 minutes until the maple syrup is bubbling and has formed a crust. Serve immediately.